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Abstract We prove that for a GNS-symmetric quantum Markov semigroup, the complete modified logarithmic Sobolev constant is bounded by the inverse of its complete positivity mixing time. For classical Markov semigroups, this gives a short proof that every sub-Laplacian of a Hörmander system on a compact manifold satisfies a modified log-Sobolev inequality uniformly for scalar and matrix-valued functions. For quantum Markov semigroups, we show that the complete modified logarithmic Sobolev constant is comparable to the spectral gap up to the logarithm of the dimension. Such estimates are asymptotically tight for a quantum birth-death process. Our results, along with the consequence of concentration inequalities, are applicable to GNS-symmetric semigroups on general von Neumann algebras. 

We study the “geometric Ricci curvature lower bound”, introduced previously by Junge, Li and LaRacuente, for a variety of examples including group von Neumann algebras, free orthogonal quantum groups [Formula: see text], [Formula: see text]-deformed Gaussian algebras and quantum tori. In particular, we show that Laplace operator on [Formula: see text] admits a factorization through the Laplace–Beltrami operator on the classical orthogonal group, which establishes the first connection between these two operators. Based on a non-negative curvature condition, we obtain the completely bounded version of the modified log-Sobolev inequalities for the corresponding quantum Markov semigroups on the examples mentioned above. We also prove that the “geometric Ricci curvature lower bound” is stable under tensor products and amalgamated free products. As an application, we obtain a sharp Ricci curvature lower bound for word-length semigroups on free group factors. 

Abstract Nitrogen (N) doped graphene materials have been synthesized using the sole precursor adenine on the Ir(111) and Ru(0001) surfaces. X-ray photoelectron spectroscopy and scanning tunneling microscopy (STM) have been used to characterize the obtained N-doped graphene materials. Several graphitic and pyridinic N dopants have been identified on the atomic scale by combining STM measurements and STM simulations based on density functional theory calculations. 

Increasing the capacity of biological nitrogen fixation (BNF) is an effective strategy to enhance food security while simultaneously reducing the carbon and nitrogen footprint of agriculture. Nanotechnology offers several pathways to enhance BNF successfully.